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Vol. 32, No. 8(2), S&M2292

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Sensors and Materials, Volume 37, Number 8(1) (2025)
Copyright(C) MYU K.K.
pp. 3419-3429
S&M4126 Research Paper
https://doi.org/10.18494/SAM5773
Published: August 8, 2025

Enhanced Green Emission in Solid-state-synthesized LaF3–LaOF:Yb3+/Tb3+ Upconversion Phosphors [PDF]

Toshihiro Nonaka, Mutsuto Yamamoto, Takahito Imai, and Shin-Ichi Yamamoto

(Received June 6, 2025; Accepted July 10, 2025)

Keywords: upconversion, LaF3, LaOF, Yb3+, Tb3+

In this study, LaF3–LaOF:Yb3+/Tb3+ was synthesized by a solid-state reaction method, and the effects of varying molar ratios on the crystal structure and optical properties of the resulting material were analyzed. Crystal structure analysis using X-ray diffraction revealed that the synthesized samples were composed of LaOF and LaF3. The photoluminescence (PL) spectra showed peaks at 486 (5D4→7F6), 541 (5D4→7F5), 583 (5D4→7F4), and 620 nm (5D4→7F3). The analysis of the pump-power dependence of the PL intensity revealed that the emission was a two-photon process, because the slopes obtained at wavelengths of 486 and 541 nm were approximately equivalent to 2. These research findings contribute to the further development of Tb³⁺-doped phosphors for temperature-sensing applications.

Corresponding author: Toshihiro Nonaka


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Cite this article
Toshihiro Nonaka, Mutsuto Yamamoto, Takahito Imai, and Shin-Ichi Yamamoto, Enhanced Green Emission in Solid-state-synthesized LaF3–LaOF:Yb3+/Tb3+ Upconversion Phosphors, Sens. Mater., Vol. 37, No. 8, 2025, p. 3419-3429.



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