pp. 233-244
S&M882 Research Paper https://doi.org/10.18494/SAM.2012.760 Published: July 9, 2012 One-Pot Synthesis and Characterization of Platinum-Coated Magnetite Nanoparticles for Magnetosensitive Catalyst [PDF] Quanguo He, Zhaohui Wu, Lei Zeng and Chunyan Huang (Received March 18, 2011; Accepted June 10, 2011) Keywords: platinum-coating, magnetosensitive catalyst, magnetite nanoparticle, nanocomposites, catalysis
Recent catalyst advances in nanoparticle-based-core synthesis have enabled the precise control of the size, shape, and composition of noble metal nanoparticles, enabling their extended catalytic activity and outside acting force responsiveness. Here, we report the design of a magnetosensitive catalyst model that consists of magnetite nanoparticles with a Pt metal coating shell (Fe3O4@Pt NPs) in a one-pot-synthesis method. The fabrication of the nanocomposite catalyst was achieved by one-stage reduction of chloroplatinic precursor ions. Monodisperse Pt-coated nanoparticles with a size of ca. 50 nm have been characterized by transmission electron microscopy, high-resolution transmission electron microscopy, energy-dispersive spectroscopy, X-ray photoelectron spectroscopy, ultraviolet-visible spectroscopy and superconducting quantum interference device magnetometry. The Fe3O4@Pt NPs obtained under appropriate conditions without any surfactant possess a saturation magnetization of about 27.3 emu g–1 and demonstrate a good magnetic response that endows them with potential magnetosensitive catalysis application. Furthermore, the design concept used in the Fe3O4@Pt NPs magnetosensitive catalyst can be extended to other metal/metal oxide compositions.
Corresponding author: Quanguo HeCite this article Quanguo He, Zhaohui Wu, Lei Zeng and Chunyan Huang, One-Pot Synthesis and Characterization of Platinum-Coated Magnetite Nanoparticles for Magnetosensitive Catalyst, Sens. Mater., Vol. 24, No. 5, 2012, p. 233-244. |