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Vol. 32, No. 8(2), S&M2292

Print: ISSN 0914-4935
Online: ISSN 2435-0869
Sensors and Materials
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Sensors and Materials, Volume 27, Number 10 (2015)
Copyright(C) MYU K.K.
pp. 1053-1058
S&M1142 Research Paper of Special Issue
https://doi.org/10.18494/SAM.2015.1179
Published: November 11, 2015

Enhancement of Methane Oxidation at the Cermet Anode Consisting of Nickel-Cobalt and Samaria-Doped Ceria in Solid Oxide Fuel Cells [PDF]

Kazunori Sato, Hiromasa Tsuchiya, Jirachaya Ayawanna and Teoh Wahtzu

(Received March 2, 2015; Accepted July 13, 2015)

Keywords: microstructure, solid solution, cell performance, overpotential, methane oxidation

The partial substitution of Co atoms for Ni atoms in the Ni-based cermet anode resulted in a decrease in the anodic overvoltage and interfacial resistance between the anode and electrolyte. This effect has been confirmed for single solid oxide fuel cells using a samaria-doped ceria (SDC) electrolyte. The results of electrochemical measurements and a product analysis by gas chromatography revealed that the direct oxidation of CH4 is enhanced by the modification of the microstructure in the cermet anode, the effect of which is combined with a sufficient oxide ion supply through the electrolyte.

Corresponding author: Kazunori Sato


Cite this article
Kazunori Sato, Hiromasa Tsuchiya, Jirachaya Ayawanna and Teoh Wahtzu, Enhancement of Methane Oxidation at the Cermet Anode Consisting of Nickel-Cobalt and Samaria-Doped Ceria in Solid Oxide Fuel Cells, Sens. Mater., Vol. 27, No. 10, 2015, p. 1053-1058.



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