pp. 915-925
S&M2862 Research Paper of Special Issue https://doi.org/10.18494/SAM.2021.3448 Published in advance: August 5, 2021 Published: March 3, 2022 In situ Visualization of Ferrous Ions Dissolved from Pure Iron Wire into Thin Frozen Aqueous Solution Films by Combination of Microscopy and Image Processing [PDF] Arinori Inagawa, Minami Maeda, and Nobuo Uehara (Received May 30, 2021; Accepted July 22, 2021) Keywords: iron, corrosion, thin ice layer, freeze-concentrated solution, image processing
The dissolution of ferrous ions from pure iron into freeze-concentrated solutions (FCSs) formed in thin films of aqueous salt solutions was visualized by a combination of in situ diffusive-reflection microscopy and image processing. An iron surface in contact with an FCS was observed with a diffusive-reflection microscope. Ferrous ions dissolved from the iron surface were complexed with 1,10-phenanthroline doped in the ice film to develop reddish complexes. In situ observation enabled us to monitor the dissolution and migration behavior of ferrous ions in the FCS. Processing of the acquired microscopic images enabled quantitative mapping of the dissolved ferrous ions. The present approach has the potential for fast screening to assess the corrosion behavior of steel materials in contact with frozen aqueous electrolytes.
Corresponding author: Arinori Inagawa, Nobuo UeharaThis work is licensed under a Creative Commons Attribution 4.0 International License. Cite this article Arinori Inagawa, Minami Maeda, and Nobuo Uehara, In situ Visualization of Ferrous Ions Dissolved from Pure Iron Wire into Thin Frozen Aqueous Solution Films by Combination of Microscopy and Image Processing, Sens. Mater., Vol. 34, No. 3, 2022, p. 915-925. |