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Vol. 34, No. 8(3), S&M3042

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Vol. 32, No. 8(2), S&M2292

Print: ISSN 0914-4935
Online: ISSN 2435-0869
Sensors and Materials
is an international peer-reviewed open access journal to provide a forum for researchers working in multidisciplinary fields of sensing technology.
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Sensors and Materials, Volume 35, Number 12(2) (2023)
Copyright(C) MYU K.K.
pp. 4167-4176
S&M3474 Research Paper of Special Issue
https://doi.org/10.18494/SAM4599
Published: December 19, 2023

Sensitive and Selective Electrochemical Sensor for Antimony Using Boron-doped Diamond Nanoparticles [PDF]

Prastika Krisma Jiwanti, Moh. Agus Rismafullah, Aning Purwaningsih, Md Shalauddin, Shamima Akhter, Wan Jeffrey Basirun, and Intan Nurul Rizki

(Received July 24, 2023; Accepted August 23, 2023)

Keywords: antimony, boron-doped diamond, screen-printed electrode, clean water

In this study, boron-doped diamond nanoparticles modified on the surface of a screen-printed electrode (SPE) were prepared for the sensitive and selective determination of Sb3+ using square wave voltammetry. The effect of electrochemical parameters such as the type of supporting electrolyte, pH, signal per background, and scan rate on the sensitivity of the sensor for the detection of Sb3+ was investigated. Under optimized conditions with an amplitude of 0.05 V, a frequency of 50 Hz, and an E-step of 0.05 V, the square wave voltammogram between −1.0 and 1.0 V gave a limit of detection of 2.41 × 10−8 M for an Sb3+ concentration range from 0.19 to 0.59 μM. The method was used to determine Sb3+ ions in river water with satisfactory results. The modified electrode displayed benefits such as high sensitivity and selectivity, long-term stability, easy preparation, and wide linear range.

Corresponding author: Prastika Krisma Jiwanti


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Cite this article
Prastika Krisma Jiwanti, Moh. Agus Rismafullah, Aning Purwaningsih, Md Shalauddin, Shamima Akhter, Wan Jeffrey Basirun, and Intan Nurul Rizki, Sensitive and Selective Electrochemical Sensor for Antimony Using Boron-doped Diamond Nanoparticles, Sens. Mater., Vol. 35, No. 12, 2023, p. 4167-4176.



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